Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Controlling stress corrosion cracking scc in order for scc to occur, we require a susceptible material, an environment that will cause cracking of that material and a high enough stress or stress intensity factor. This form of corrosion is controlled by maintaining low chloride ion and oxygen content in the environment and use of low carbon steels. Chloride stress corrosion cracking and 316 stainless steel edstainless materials 20 jul 11 23.
Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. The micrograph on the left x300 illustrates scc in a 316 stainless steel chemical processing piping system. Elevated stress susceptible material corrosive environment surface contamination by atmospheric chlorides sufficient humidity epri has a multiyear project to. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion.
Effects of marine environments on stress corrosion cracking. Although no stainless steel grade is totally immune to chloride scc, the relative resistance of stainless steels varies substantially. Stress corrosion cracking in a brewery paul mueller company. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of. Mechanism of chloride stress corrosion cracking of austenitic. Chloride stress corrosion cracking cl scc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Corrosionpedia what is chloride stress corrosion cracking. Meletis and hochman 99 reported crystallographic tgscc for 99. Stress corrosion cracking poses a serious threat to the integrity of a natural gas plant and the company responded to this threat by launching a comprehensive initiative to determine the causes and to adopt best practices for preventing. Stress corrosion cracking of sensitized type 304 stainless. The austenitic family is more vulnerable than any other. There are, consequently, a number of approaches that we can use to prevent scc, or at least to give an acceptable lifetime. The part is stressed by an applied load or by residual stress. A pipelines defense against chloride stress corrosion cracking scc depends on the family of stainless steel from which it comes.
It is recognized that stress corrosion cracking of stainless steels occurs commonly by chloride solutions 95% of chloride scc cases being by sodium chloride. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Pitting corrosion and scc resistance was the highest for sa weldment, which was attributed to. Stresscorrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. Stress corrosion cracking international institute of. Stress corrosion cracking of an austenitic stainless steel. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Transgranular stress corrosion cracking an overview. Stress corrosion cracking susceptibility of 304l substrate.
It also excludes intercrystalline or transcrystalline corrosion, which can disintegrate an alloy without applied or residual stress. Pitting or crevice corrosion can occur on most stainless steel grades. External chloride stress corrosion cracking of stainless. Ctlchloride stress corrosion cracking of buried stainless. It can be detrimental to austenitic stainless steels, one of the main reasons.
Stress corrosion cracking scc is a sudden cracking and failure of a component without deformation. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. This paper presents the role of addition of nitrite ions in susceptibility of a super duplex stainless steel, saf 2507 to stress corrosion cracking scc in chloride environment, which has a. Stress corrosion cracking of stainless steels and nickel alloys at. The use of material susceptible to stress corrosion cracking scc a precursor of stress corrosion cracking in chloridebearing environments is pitting corrosion, occurring if the stainless steel is not sufficiently resistant to pitting. Corrosionpedia what is stress corrosion cracking scc. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k with relative humidity rh of.
Chloride stress corrosion involves selective attack of a metal along its grain boundaries. Selection of stainless steels for water tank applications. The most common environmental exposure condition responsible for scc of stainless steels is the presence of chlorides. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. There is an additional risk of stress corrosion cracking scc at. In general, this test method is more useful for stainless steels than the boiling magnesium chloride test of practice g36. Laboratory tests were conducted to investigate the stress corrosion cracking scc of 304l stainless steel used to construct the containment vessels for the storage of plutoniumbearing materials. Previously, it was generally considered that an elevated temperature was necessary for scc to occur. Although no stainless steel grade is totally immune. Pdf stress corrosion cracking scc of nickelbased alloys. Chloride stress corrosion cracking in austenitic stainless steel. Austenitic stainless steels chloride induced stress. Stainless steel grades, such as the 304 or 316 types are generally suitable for storing and handling cold or unheated drinking towns waters. A corrosive medium especially chloride bearing or hydrogensulphide h 2 s media.
Clscc chloride stress corrosion cracking mechanism china. If the cause of failure is known, then the conditions leading to the corrosion should be eliminated or the repair should use material more resistant to scc. Tp304 ss and tp316 ss can occur when water containing chloride is present underneath insulation, external metal skin temperature exceeds approximately 50 c, and there is no surface protection or when the protective coating e. It has been reported that the environmentalfracture is discontinuous at the micron scale 4. The combination of tensile stress and a specific corrosive environment can crack stainless steels. Chloride promoted stress corrosion cracking occurs when three conditions are satisfied. Chloride stress corrosion cracking in austenitic stainless. A material failure may be accelerated by the combined effect of corrosion and mechanical stress. Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows.
Stress corrosion cracking facts and how to reduce the. Then, the stress corrosion cracking mechanism for various materials in conditions that are susceptible is discussed in detail. This excludes corrosionreduced sections that fail by fast fracture. Alternative tests for laboratory studies of stress corrosion cracking.
Pdf stress corrosion cracking of austenitic stainless. Polythionic acid stress corrosion cracking deterioration. Once stainless steel experiences stress corrosion cracking there is no method to reverse the process. Astm g123 002015 standard test method for evaluating. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic. Stainless steels are more resistant to general corrosion compared with carbon steel.
Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. Chloride induced stress corrosion cracking ciscc in. Introduction stress corrosion cracking scc of austenitic 304 stainless steel in chloride environment is a common problem in industries. The chloride stresscorrosion cracking behavior of stainless steels. This diagram figure 1 is analogous to a similar diagram for caustic. The austenitic stainless steel tubes in these services can be susceptible to polythionic acid stress corrosion cracking. Chloride induced stress corrosion cracking ciscc of stainless steel reactor components has occurred when three elements are all present. Stress corrosion cracking scc in stainless steels request pdf. Stress corrision cracking is a relatively rare form of corrosion, which requires a specific combination of tensile stress, temperature and corrosive species, often the chloride ion, for it to occur. Chloride stress corrosion cracking clscc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Therefore, the scc concerns for spent fuel storage canisters identified in a november 2004 presentation by nuclear and. The observed crack propaga tion is the result of the combined and synergistic interaction of mechanical stress and corrosion re actions.
This safety alert highlights the issue of chloride stress corrosion cracking which has been found to affect stainless steel grade 316316l lokring pipe connectors. Key corrosion mechanisms explained stainless steel world. Behaviour of stress corrosion cracking of austenitic stainless. The mechanism of chloride stress corrosion cracking clscc is complex and the current understanding is discussed in section 5 of this report. Stress corrosion cracking scc is a common issue with many specialty alloys.
Scc is a form of corrosion that occurs in nearly all alloys, including the grades of stainless steel commonly used in brewery equipment types 304, 304l, 316, and 316l. For example, chloride stress corrosion cracking of austenitic stainless steel has been experienced in hotwater jacketed pipes carrying molten chocolate in the food industry. Thermal stresses due to varying operating temperatures, ineffective expansion bellows, or residual stresses from welding have all been found capable of promoting stress corrosion cracking. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. The most common type is transgranular stresscorrosion cracking, scc, that may develop in concentrated chloridecontaining environments.
Pitting and stress corrosion cracking scc studies on the 316n stainless steel ss weldments in aswelded aw and thermally aged solution annealing sa, 550 c4 h and 750 c1 h conditions were carried out in acidic and acidic chloride media. Austenitic stainless steels chloride induced stress corrosion cracking cscc chumpes petroleum 16 mar 18 10. This mode of attack is termed stress corrosion cracking scc. Pitting and stress corrosion cracking studies on aisi type. Stress corrosion cracking is the cracking of a susceptible metal under the mixed. Intergranular stress corrosion cracking of welded steel twi. Jan 08, 2002 the duplex stainless steels, on the other hand, are more resistant to stress corrosion cracking scc than austenitic grades. Pitting corrosion has been reported from household bleach spills on stainless steel 304 type sinks in domestic environments. It has been found that scc resistance can be improved in some cases with the application of compressive stress to the material at risk. Chloride induced stress corrosion cracking of stainless. The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. In this chapter, the conditions for the occurrence of scc are first introduced.
The most common type is transgranular stress corrosion cracking, scc, that may develop in concentrated chloride containing environments. Apr 14, 2015 this safety alert highlights the issue of chloride stress corrosion cracking of stainless steel lokring pipe connectors and advises dutyholders on actions required. Localized corrosion and stress corrosion cracking of stainless steels. The best way to cope with scc problems is to replace all or part of the damaged equipment. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride. Chlorideinduced stresscorrosion cracking scc is one of the failure modes of stainless steels. Chloride stress corrosion cracking clscc of stainless. Its resistance relates to the amount of nickel contained in the steel, with most vulnerable austenitic categories having nickel contents ranging from 8 to. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Chloride stress corrosion cracking methods of minimizing. Mechanism of chloride stress corrosion cracking of. Electrochemical studies were made in aqueous licl, mgcl 2, and mgbr 2 solutions and in zncl 2 kcl molten salt to clarify the corrosion reactions related to stress corrosion cracking scc of austenitic stainless steel and to better define environmental variables critical to the occurrence of chloride scc. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15. Supermartensitic stainless steels smss, including both lean grades without molybdenum and high grades with 2% molybdenum, have shown sensitivity to intergranular corrosion or stress corrosion cracking igscc in weld hazs during laboratory testing in chloride solutions acidified with co 2.
Overview the fe21cr24ni6mo uns n08367 alloy was designed to be a seawater resistant alloy and has been successfully used in a multitude of marine and offshore applications including process piping systems, heat exchanger equipment. Scc can occur typically in hot water tanks or swimming pools. Influence of grinding operations on surface integrity and. Essentially clscc involves a combination of the electrochemistry of metal dissolving over a highly localised area, i. It is difficult to control the temperature, while changing pipe material or eliminating residual stresses associated with welding and forming the pipework is costly and. Stress corrosion cracking the international institute of. Pdf chloride induced stress corrosion cracking of type 304. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Chloride stress corrosion cracking is a well known form of scc, typically caused. There is an additional risk of stress corrosion cracking scc at higher temperatures. Structural failure due to scc can be very unpredictablefailure could occur after as little as a few hours of exposure, or the equipment could continue to function normally for. Effects of marine environments on stress corrosion. Susceptibility assessment criteria for chlorideinduced. For example, copper and its alloys are susceptible to ammonia compounds, mild steels are susceptible to alkalis and stainless steels are susceptible to chlorides.
Stress corrosion cracking scc is a progressive fracturing that occurs in metals as a result of the combined influence of tensile stress and a corrosive environment. Chloride stress corrosion cracking and 316 stainless steel. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. With regard to the safe temperature for carbon steel, the reader should look at the curve in figure 1. Stress corrosion cracking scc stainless steel tubing. Note that tsujikawa found that the critical temperature could range from.
As its name suggests, scc takes the form of a network of cracks that eventually will lead to sudden, catastrophic failure in your tanks. Intergranular and transgranular stress corrosion cracking of the aisi 316l stainless steel at polythionic acid environment 8. Significant scc could affect the ability of the spent fuel storage canisters to perform their confinement function during the initial license or license renewal storage periods. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Abstract the purpose of this paper is to present a condensed summary of the work done by dolphin energy on chloride stress corrosion cracking cl scc. They are as susceptible to failure due to chlorideinduced corrosion.
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